FFMPEG Make Video
Having downloaded FFMPEG and prepared your video (for example myvideo.avi)
ffmpeg -i myvideo.avi -r 30 -s 256x256 myvideo.roq
Will convert to .roq format for use in your map. A simple shader can be constructed which can be applied to a simple brush face.
textures/underwater/videowall { qer_editorImage textures/mymap/video.jpg surfaceparm nolightmap { videoMap myvideo.roq rgbGen identity } }
You'll need to put the video in the video folder (top level).